By C.B. Anfinsen, John T. Edsall, Frederic M. Richards, David S. Eisenberg and George Lorimer (Eds.)

ISBN-10: 0120342448

ISBN-13: 9780120342440

Reports present issues within the box of protein chemistry. the topics lined comprise the constitution and mechanism of heat-shock-related proteins, the position of prolylisomerases in protein folding, and the mechanism of enzymic and nonenzymic prolylcis-transisomerization.

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1985). “Enzyme Structure and Function,” pp. 109-1 1 1 . Freeman, New York. Fischer, C. (1989). Nova Acta Leopold. 61, 35-53. , and Mech, C. (1984). Ezomed. Eiochzm. Acta 43, 1101-1 1 1 1 . , and Bang, H. (1989a). FEES Lett. 250, 267-270. , and Schmid, F. X. (1989b). Nature (London) 337, 476-478. , and Schowen, R. L. (1985). Eioorg. Chem. 13, 57-61. Galardy, R. , and Liakopoulou-Kyriakides, M. Int. J . P e p . ProleinRes. 20,144-148. Gerig, J. T. (1971). Eiopolymers 10, 2443-2453. , and Wurthrich, K.

R The acceleration of the different phases of the refolding reactions are compared with the acceleration of the isomerization of the assay peptide. " Phase 1 of the refolding reaction of RCM-RNase TI and RNase TI, respectively. 'Phase 2 of the refolding reaction of RCM-RNase TI and RNase TI, respectively. Isomerization of the assay peptide Suc-Ala-Ala-Pro-Phe-ONa. Ir K values for the different refolding reactions in the presence of 152 Klml PPI. Ratio of the K values for the respective refolding reaction and for the catalysis of the isomerization of the assay peptide.

Catalysis of Slow-Folding Steps IV. V. VI. B. Dependence on Substrate Concentration of Folding Catalysis C . Efficiency of Catalysis . . D. Native State Isomerization ...... 25 26 26 27 28 30 31 31 33 33 34 36 36 37 40 42 42 44 44 46 48 51 VII. VIII. IX. References . . . . . . . . . . . . . . . . . . . . . . . . . . . Note Added in Proof 51 54 54 55 59 59 60 61 62 65 I . INTRODUCTION Cis-trans isomerizations of Xaa-Pro peptide bonds are involved in the refolding reactions of many proteins.

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Accessory Folding Proteins by C.B. Anfinsen, John T. Edsall, Frederic M. Richards, David S. Eisenberg and George Lorimer (Eds.)


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