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Extra info for Advanced chemical oxidation treatment of dye wastewater and remediation of chlorinated aromatic

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It was found (11) that solutions of ytterbium in liquid ammonia are able to give Birch-type reactions on aromatic systems (eq. [1) ). (5 OMe Yb NH3 ... , C0 2H 0 cf Yb .. I NH3 [1] I Triple bonds are cleanly reduced to trans olefins (eq. [2] ). Ph-C :C-Ph .. [2] trans _ Ph-CH=CH-Ph The conjugated C=C double bonds of enone are also reduced as well as the carbonyl group if the reduction is performed in a mixture of liquid NH3 and ethanol. In absence of ethanol it is the pinacol which is obtained Ceq.

91 (19691 775. 189. Organometal. , 259 (1983) 91. 190. , (1980) 810. 191. H. , 19 (1980) 2999. 192. , 103 (1981) 6507. ==193. , 106 (1984) 4270. 194. , 21 (1982) 2647. -195. , (1970) 244. 196. , A, (1971) 1931, 197. Letters, 7 (1971) 755. 198. ; 35 (1982) 941. 199. , 146 TT978) c43. 200. , 20~1981) c4. , 112 (1976) Cl. 202. , 135 (1977) 103. =-= 203. Organometal. , 182 (1979) 121. 204. , 36 (1983) 43. 205. Mac Kinnon, Tetrahedron Letters, 25 (1984) 783. 206. , 262 (1984) C35. 207. P. , 255 (1983) C5.

Yokoyama, Tetrahedron Letters, 22 (1981) 4987. 225. Yokoyama, Tetrahedron Letters, 23 (1982) 1353. 226. Yokayama, Tetrahedron Letters, 24 (1983) 5233. 227. , (1984) 163. 228. Yokoyama, Yuki Gosei Kagaku Kyokaishi, ~ (1984) 143. KAGAN Laboratoire de Synthese Asymetrique, associe au CNRS (UA 255) Batiment 420 Universite Paris-Sud, 91405 Orsay, France. I. INTRODUCTION Organic synthesis remains of major interest for the production of a large number of compounds, especially in the phaIll1aceuticill fiE:\ld o~ ~o~ high value added products.

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Advanced chemical oxidation treatment of dye wastewater and remediation of chlorinated aromatic


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