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Extra info for Advanced chemical oxidation treatment of dye wastewater and remediation of chlorinated aromatic
It was found (11) that solutions of ytterbium in liquid ammonia are able to give Birch-type reactions on aromatic systems (eq. [1) ). (5 OMe Yb NH3 ... , C0 2H 0 cf Yb .. I NH3  I Triple bonds are cleanly reduced to trans olefins (eq.  ). Ph-C :C-Ph ..  trans _ Ph-CH=CH-Ph The conjugated C=C double bonds of enone are also reduced as well as the carbonyl group if the reduction is performed in a mixture of liquid NH3 and ethanol. In absence of ethanol it is the pinacol which is obtained Ceq.
91 (19691 775. 189. Organometal. , 259 (1983) 91. 190. , (1980) 810. 191. H. , 19 (1980) 2999. 192. , 103 (1981) 6507. ==193. , 106 (1984) 4270. 194. , 21 (1982) 2647. -195. , (1970) 244. 196. , A, (1971) 1931, 197. Letters, 7 (1971) 755. 198. ; 35 (1982) 941. 199. , 146 TT978) c43. 200. , 20~1981) c4. , 112 (1976) Cl. 202. , 135 (1977) 103. =-= 203. Organometal. , 182 (1979) 121. 204. , 36 (1983) 43. 205. Mac Kinnon, Tetrahedron Letters, 25 (1984) 783. 206. , 262 (1984) C35. 207. P. , 255 (1983) C5.
Yokoyama, Tetrahedron Letters, 22 (1981) 4987. 225. Yokoyama, Tetrahedron Letters, 23 (1982) 1353. 226. Yokayama, Tetrahedron Letters, 24 (1983) 5233. 227. , (1984) 163. 228. Yokoyama, Yuki Gosei Kagaku Kyokaishi, ~ (1984) 143. KAGAN Laboratoire de Synthese Asymetrique, associe au CNRS (UA 255) Batiment 420 Universite Paris-Sud, 91405 Orsay, France. I. INTRODUCTION Organic synthesis remains of major interest for the production of a large number of compounds, especially in the phaIll1aceuticill fiE:\ld o~ ~o~ high value added products.
Advanced chemical oxidation treatment of dye wastewater and remediation of chlorinated aromatic